Nataliia Pentiuk graduated with honors from the medical faculty at Vinnytsia Medical Institute in 1996. In October 1998, she completed a full master's course at the Department of faculty therapy at Vinnytsia State Medical University. From 1998 to 1999, she worked as a laboratory assistant at the Department of Infectious Diseases of Vinnytsia State Medical University named after Pirogov. From September 1999 to August 2006, she worked as an assistant professor at the Department of Infectious Diseases. In 2001, she defended her Ph.D. thesis entitled: "Nephrotoxicity of nonsteroidal anti-inflammatory drugs and its correction with trimetazidine", specialty 14.01.28 - clinical pharmacology (dissertation advisor - prof. Stanislavchuk M.A.). From September 2006 to May 2012, she worked as an assistant professor at the Department of Propaedeutics of internal medicine. In 2011, she defended her thesis for the degree of Doctor of Medicine entitled: "Hyperhomocysteinemia and associated metabolic and vascular factors of the liver fibrosis and cirrhosis progression: possibilities of pathogenetic therapy" – 14.01.36 – gastroenterology (doctoral supervisor - prof. Kharchenko N.V.). From 2012 to 2018, she worked as an associate professor of the Department of Propaedeutics of internal medicine at National Pirogov Memorial Medical University, Vinnytsia, and from 2018 to 2023 – as a professor of the department. From 2015 to 2021, she was a member of the Specialized Academic Council D 05.600.05 for the defense of a Ph.D. thesis in specialties 03.00.07 – microbiology, 01.14.32 – medical biochemistry.
From February 2023, he heads the Department of Propaedeutics of internal medicine at National Pirogov Memorial Medical University, Vinnytsia.
She delivers lectures on propaedeutics of internal medicine and supervises students' scientific work. She conducts seminar classes with interns and graduate students.
Since 2014, he has had a higher qualification degree in internal medicine. She specializes in rheumatology (2017) and gastroenterology (2019).
She consults patients and participates in consiliums in the clinical therapeutic departments #1 and #2, the infectious department, and the ICUs #1 and #2 of the Vinnytsia City Clinical Hospital #1. She makes rounds of patients in the clinical therapeutic department #1. She participates in more than 30 international clinical multicenter randomized phase I-IV trials, in 5 of them – as principal investigator. She is a permanent member of the European Association for the Study of the Liver (EASL).
She conducts clinical case analysis, as a reviewer participates in pathological-anatomical conferences.
She is the author of 117 printed works, including 8 publications cited in Scopus or Web o Science, 26 publications of an educational and methodological nature, and 62 specialized publications. She has 5 patents in Ukraine for a utility model. She participates in the defense of dissertations as an official opponent and reviewer. She performs scientific supervision of a Ph.D. student. The scientific and educational experience of 24 years.

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